Action of Acetyl Chloride.
نویسندگان
چکیده
منابع مشابه
3-Acetyl-2,4-dimethylquinolin-1-ium chloride
In the title salt, C13H14NO(+)·Cl(-), the dihedral angle between the fused ring system (r.m.s. deviation = 0.039 Å) and the attached aldehyde group is 75.27 (16)°. In the crystal, the cation and anion are linked by an N-H⋯Cl hydrogen bond and the resulting pairs are connected into four-ion aggregates by π-π inter-actions between the C6 and pyridinium rings [3.6450 (9) Å] of inversion-related qu...
متن کاملInhibition of rat liver acetyl CoA carboxylase by chloride.
The activity of acetyl CoA carboxylase in both crude and purified rat liver preparations was reduced in the presence of sodium or potassium chloride and increased in the presence of potassium acetate. The chloride inhibition was not competitive with bicarbonate. The use of Trischloride buffer did not alter the apparent pH optimum of the enzyme when compared with Tris-acetate buffer.
متن کامل3-Acetyl-2-methyl-4-phenylquinolin-1-ium chloride
An N-H⋯Cl hydrogen bond connects the ions in the title salt, C(18)H(16)NO(+)·Cl(-). The quinolin-1-ium residue is almost planar (r.m.s. deviation = 0.020 Å) but both the acetyl group [O-C-C-C torsion angle = 62.73 (17)°] and adjacent benzene ring [C-C-C-C torsion angle = -104.06 (14)°] are twisted out of this plane; the acetyl and benzene substituents are non-parallel [dihedral angle = 66.16 (7...
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This work uses velocity map imaging to determine the barrier height for acetyl radical, CH3CO, dissociation to CH3 + CO. Photodissociation of acetyl chloride at 235 nm generates acetyl radicals with an internal energy distribution spanning this barrier. We determine the velocity and internal energy distribution of all nascent acetyl radicals, stable and unstable, by measuring the velocities of ...
متن کاملAssessing an impulsive model for rotational energy partitioning to acetyl radicals from the photodissociation of acetyl chloride at 235 nm.
This work uses the photodissociation of acetyl chloride to assess the utility of a recently proposed impulsive model when the dissociation occurs on an excited electronic state that is not repulsive in the Franck-Condon region. The impulsive model explicitly includes an average over the vibrational quantum states of acetyl chloride when it calculates an impact parameter for fission of the C-Cl ...
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ژورنال
عنوان ژورنال: Journal of the American Chemical Society
سال: 1906
ISSN: 0002-7863,1520-5126
DOI: 10.1021/ja01974a010